No. Dvd's are "tangible" products that you ship. So they don't qualify as "digital items" under eBay guidlines. I was talking more specifically about "ebooks" and "software" a purchaser either downloads from a link on a page that is set up with eBay and PayPal or that you state on that Page they see after a purchase that the item will be emailed to them.
That may work for say a "small" ebook or small in size (kilobytes) piece of software. I guess it could also be "picture", but I wouldn't know who would buy a picture of something to download...at least a legal one anyway. But hey, if you can sell a "grilled cheese sandwhich" that someone states has the picture of th Virgin Mary burnt into it for $20,000...maybe you can take a picture of a "UFO" or an "Alien" or "Big Foot", (gee you got me thinking here), or something and sell it...who knows